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Frozen Battery update — Parallax Forums

Frozen Battery update

ArchiverArchiver Posts: 46,084
edited 2002-12-14 21:28 in General Discussion
I was able to revive my frozen battery just by placing it on the
charger for a few days. It took a day before it started to charge but
once it broke down the sulfates on the plates it really started to take
a decent charge.

No pulser was needed. Just a cheap shumacher charger. Save your stamps
for furnace filter reminders : )

Jason

Comments

  • ArchiverArchiver Posts: 46,084
    edited 2002-12-14 06:38
    Please folks - Do not follow Jason's example by placing a frozen battery
    on a charger.

    They can explode and you can be severely injured or killed. This
    warning is normally found in every battery charger manual.

    When in the Navy and attending electronics school, the instructors had
    stated that for each warning that was placed in the manual someone had
    died. That if we should die, from some new blunder on our part, an
    appropriate warning would be added in the future.

    Made sense to me, I read and adhere to warnings.

    Jason I'd recommend you for a Darwinian award but I see that you are
    still alive.

    Desulfators are not a cure for frozen batteries. Desulfators remove the
    large sulfate crystal growths that cannot be removed by charging. These
    are the crystal formations that eventually grow to the point of lead
    acid battery failure and accounts for over 80% of the failure modes.

    If you would like to see the crystals with your naked eye, go out at
    night and shine a flashlight down into a flooded cell. If your battery
    is along the path to this type of failure you will see something pretty
    like diamond dust that sparkles.

    I am always disappointed in people that run around attempting to
    dissuade folks from learning or trying anything new.





    "jbirnsch " wrote:
    >
    > I was able to revive my frozen battery just by placing it on the
    > charger for a few days. It took a day before it started to charge but
    > once it broke down the sulfates on the plates it really started to take
    > a decent charge.
    >
    > No pulser was needed. Just a cheap shumacher charger. Save your stamps
    > for furnace filter reminders : )
    >
    > Jason
    >
    > To UNSUBSCRIBE, just send mail to:
    > basicstamps-unsubscribe@yahoogroups.com
    > from the same email address that you subscribed. Text in the Subject and Body
    of the message will be ignored.
    >
    >
    > Your use of Yahoo! Groups is subject to http://docs.yahoo.com/info/terms/
  • ArchiverArchiver Posts: 46,084
    edited 2002-12-14 07:17
    Don,

    I thawed the battery before I placed it on the charger. I also topped
    it off with water to the fill line for each cell. The plates were
    deposited with a white looking growth. I set the charger to 2A charge
    ant left it there for a day. At first it took very little charge,
    around 40mA but after a couple hours it was up to 400mA. The next day I
    set it to 10 A charge. I left it there for 2 days. By the end of the
    second day the battery was bubbling and slightly warm. Now when I
    looked at the plates they were clean and free from deposits. Installed
    it into the snowmobile and it started right up.

    Where do you see the danger in this????

    Yes, lead acid battery's will explode but only if a spark is generated
    while charging at high amp rating like 50 A. It will ignite the
    hydrogen gas from the charging process.

    Any time a person jump starts a car there at risk of an explosion.

    All as I am saying that sometimes you get lucky and save a few bucks.

    Darwin award!!!!! Whatever.......

    I grew up on a dairy farm. If anyone had more a chance to get maimed or
    killed it would be me. I still have all of my fingers and toes.

    Jason

    --- In basicstamps@yahoogroups.com, Don Denhardt <dondenhardt@y...>
    wrote:
    > Please folks - Do not follow Jason's example by placing a frozen battery
    > on a charger.
    >
    > They can explode and you can be severely injured or killed. This
    > warning is normally found in every battery charger manual.
    >
    > When in the Navy and attending electronics school, the instructors had
    > stated that for each warning that was placed in the manual someone had
    > died. That if we should die, from some new blunder on our part, an
    > appropriate warning would be added in the future.
    >
    > Made sense to me, I read and adhere to warnings.
    >
    > Jason I'd recommend you for a Darwinian award but I see that you are
    > still alive.
    >
    > Desulfators are not a cure for frozen batteries. Desulfators remove the
    > large sulfate crystal growths that cannot be removed by charging. These
    > are the crystal formations that eventually grow to the point of lead
    > acid battery failure and accounts for over 80% of the failure modes.
    >
    > If you would like to see the crystals with your naked eye, go out at
    > night and shine a flashlight down into a flooded cell. If your battery
    > is along the path to this type of failure you will see something pretty
    > like diamond dust that sparkles.
    >
    > I am always disappointed in people that run around attempting to
    > dissuade folks from learning or trying anything new.
    >
    >
    >
    >
    >
    > "jbirnsch " wrote:
    > >
    > > I was able to revive my frozen battery just by placing it on the
    > > charger for a few days. It took a day before it started to charge but
    > > once it broke down the sulfates on the plates it really started to take
    > > a decent charge.
    > >
    > > No pulser was needed. Just a cheap shumacher charger. Save your stamps
    > > for furnace filter reminders : )
    > >
    > > Jason
    > >
    > > To UNSUBSCRIBE, just send mail to:
    > > basicstamps-unsubscribe@yahoogroups.com
    > > from the same email address that you subscribed. Text in the Subject and
    Body of the message will be ignored.
    > >
    > >
    > > Your use of Yahoo! Groups is subject to http://docs.yahoo.com/info/
    terms/
  • ArchiverArchiver Posts: 46,084
    edited 2002-12-14 07:39
    Good to hear. The thawing was not part of your original post. As such
    it constituted an incomplete procedure that is a well known recipe for
    disaster.

    You may find in the future it is best not to add distilled water to the
    full mark prior to recharging operations. Should the battery achieve a
    gaseous state, some of the bubbles will cling to the plates and
    separators.

    This results in displacing electrolyte, blowing electrolyte out the
    vents if you have forgotten to remove the vent caps. Or just
    overflowing electrolyte. Usually it is best to refrain from adding
    distilled water until the battery is gassing or has just finished the
    charge cycle. It is ok to cover exposed plates though.

    Frozen batteries can explode when electrolyte in the center which has
    not been frozen gasses and builds up enormous pressures.

    All that is required for a volatile hydrogen/oxygen pocket to form
    around a battery is for the charging voltage to be in the gassing
    range. Batteries can gas at low amperage charge rates if they are at a
    fairly high State of Charge (SOC).

    Usually when jump starting a car, if there is any kind of a wind
    present, it will sweep volatile gases away and you are safe. The hazard
    occurs when you attempt this in a garage or a day that there is little
    to no air movement.

    "jbirnsch " wrote:
    >
    > Don,
    >
    > I thawed the battery before I placed it on the charger. I also topped
    > it off with water to the fill line for each cell. The plates were
    > deposited with a white looking growth. I set the charger to 2A charge
    > ant left it there for a day. At first it took very little charge,
    > around 40mA but after a couple hours it was up to 400mA. The next day I
    > set it to 10 A charge. I left it there for 2 days. By the end of the
    > second day the battery was bubbling and slightly warm. Now when I
    > looked at the plates they were clean and free from deposits. Installed
    > it into the snowmobile and it started right up.
    >
    > Where do you see the danger in this????
    >
    > Yes, lead acid battery's will explode but only if a spark is generated
    > while charging at high amp rating like 50 A. It will ignite the
    > hydrogen gas from the charging process.
    >
    > Any time a person jump starts a car there at risk of an explosion.
    >
    > All as I am saying that sometimes you get lucky and save a few bucks.
    >
    > Darwin award!!!!! Whatever.......
    >
    > I grew up on a dairy farm. If anyone had more a chance to get maimed or
    > killed it would be me. I still have all of my fingers and toes.
    >
    > Jason
    >
    > --- In basicstamps@yahoogroups.com, Don Denhardt <dondenhardt@y...>
    > wrote:
    > > Please folks - Do not follow Jason's example by placing a frozen battery
    > > on a charger.
    > >
    > > They can explode and you can be severely injured or killed. This
    > > warning is normally found in every battery charger manual.
    > >
    > > When in the Navy and attending electronics school, the instructors had
    > > stated that for each warning that was placed in the manual someone had
    > > died. That if we should die, from some new blunder on our part, an
    > > appropriate warning would be added in the future.
    > >
    > > Made sense to me, I read and adhere to warnings.
    > >
    > > Jason I'd recommend you for a Darwinian award but I see that you are
    > > still alive.
    > >
    > > Desulfators are not a cure for frozen batteries. Desulfators remove the
    > > large sulfate crystal growths that cannot be removed by charging. These
    > > are the crystal formations that eventually grow to the point of lead
    > > acid battery failure and accounts for over 80% of the failure modes.
    > >
    > > If you would like to see the crystals with your naked eye, go out at
    > > night and shine a flashlight down into a flooded cell. If your battery
    > > is along the path to this type of failure you will see something pretty
    > > like diamond dust that sparkles.
    > >
    > > I am always disappointed in people that run around attempting to
    > > dissuade folks from learning or trying anything new.
    > >
    > >
    > >
    > >
    > >
    > > "jbirnsch " wrote:
    > > >
    > > > I was able to revive my frozen battery just by placing it on the
    > > > charger for a few days. It took a day before it started to charge but
    > > > once it broke down the sulfates on the plates it really started to take
    > > > a decent charge.
    > > >
    > > > No pulser was needed. Just a cheap shumacher charger. Save your stamps
    > > > for furnace filter reminders : )
    > > >
    > > > Jason
    > > >
    > > > To UNSUBSCRIBE, just send mail to:
    > > > basicstamps-unsubscribe@yahoogroups.com
    > > > from the same email address that you subscribed. Text in the Subject and
    Body of the message will be ignored.
    > > >
    > > >
    > > > Your use of Yahoo! Groups is subject to http://docs.yahoo.com/info/
    > terms/
    >
    > To UNSUBSCRIBE, just send mail to:
    > basicstamps-unsubscribe@yahoogroups.com
    > from the same email address that you subscribed. Text in the Subject and Body
    of the message will be ignored.
    >
    >
    > Your use of Yahoo! Groups is subject to http://docs.yahoo.com/info/terms/
  • ArchiverArchiver Posts: 46,084
    edited 2002-12-14 16:13
    Interesting post.

    I would assume that the battery had not died from sulphantion from
    normal use.

    I would also assume that the battery was in good condition before it
    became frozen. it may not have had a good charge, but it must not
    have been insulated with highly sulphenated deposits.

    Obviously, the battey did not suffer catastrophic mechanical failure
    from the freezing. it MAY have suffered stress fractures.

    What I can figure out from the posts is that

    A) deposits DO revert or should I say, the sulphur changes phase from
    a crystaline solid to a dissolved form. The presence of white
    deposits and lack of them after chargeing indicate that.

    B) People who live in rural areas are more resourcefull becasue they
    need to be. and are often smart enough to think the problem all the
    way thru. Those who not think it all the way thru offer use neat
    catch phrases like don't run with sizzors. or check the polarity of
    the cap before you apply power. Puts new meaning into "you are only
    as safe as your most unsafe act"

    C) Jason has multiple setting on his charger. I have a trickle
    charger for my motorcycle and a 30 amp fully automatic for my car.

    D) we don't have any "Ted Kennedy" awards for people who happen to
    kill others by their dumb mistakes. I don't think battery charging
    constitues a nomination for a Darwin award, unless you were doing in
    the charging in the basement next to your open paint thinner, while
    doing a whole body indoor tanning with a kerosene based tanning gel,
    and ignoring the hissing from your home made hydrogen fuelcell
    hydrogen generator and then tapping the wires from the charger to
    test polarity. On your wife's birthday.

    Now my question.

    I was told that when you take your dead battery to the service
    station and they put on the 50amp or 250 amp charger, it will weaken
    or destroy it.

    Accepting that non-bonded, non-crystalized sulphur deposits will be
    be flaked off, not re-disolved, what else would this do ?

    Do we expose ourselves to the same problem with our gel cells ?

    Dave

















    --- In basicstamps@yahoogroups.com, "jbirnsch <jbirnsch@v...>"
    <jbirnsch@v...> wrote:
    > Don,
    >
    > I thawed the battery before I placed it on the charger. I also
    topped
    > it off with water to the fill line for each cell. The plates were
    > deposited with a white looking growth. I set the charger to 2A
    charge
    > ant left it there for a day. At first it took very little charge,
    > around 40mA but after a couple hours it was up to 400mA. The next
    day I
    > set it to 10 A charge. I left it there for 2 days. By the end of
    the
    > second day the battery was bubbling and slightly warm. Now when I
    > looked at the plates they were clean and free from deposits.
    Installed
    > it into the snowmobile and it started right up.
    >
    > Where do you see the danger in this????
    >
    > Yes, lead acid battery's will explode but only if a spark is
    generated
    > while charging at high amp rating like 50 A. It will ignite the
    > hydrogen gas from the charging process.
    >
    > Any time a person jump starts a car there at risk of an explosion.
    >
    > All as I am saying that sometimes you get lucky and save a few
    bucks.
    >
    > Darwin award!!!!! Whatever.......
    >
    > I grew up on a dairy farm. If anyone had more a chance to get
    maimed or
    > killed it would be me. I still have all of my fingers and toes.
    >
    > Jason
    >
    > --- In basicstamps@yahoogroups.com, Don Denhardt <dondenhardt@y...>
    > wrote:
    > > Please folks - Do not follow Jason's example by placing a frozen
    battery
    > > on a charger.
    > >
    > > They can explode and you can be severely injured or killed. This
    > > warning is normally found in every battery charger manual.
    > >
    > > When in the Navy and attending electronics school, the
    instructors had
    > > stated that for each warning that was placed in the manual
    someone had
    > > died. That if we should die, from some new blunder on our part,
    an
    > > appropriate warning would be added in the future.
    > >
    > > Made sense to me, I read and adhere to warnings.
    > >
    > > Jason I'd recommend you for a Darwinian award but I see that you
    are
    > > still alive.
    > >
    > > Desulfators are not a cure for frozen batteries. Desulfators
    remove the
    > > large sulfate crystal growths that cannot be removed by
    charging. These
    > > are the crystal formations that eventually grow to the point of
    lead
    > > acid battery failure and accounts for over 80% of the failure
    modes.
    > >
    > > If you would like to see the crystals with your naked eye, go out
    at
    > > night and shine a flashlight down into a flooded cell. If your
    battery
    > > is along the path to this type of failure you will see something
    pretty
    > > like diamond dust that sparkles.
    > >
    > > I am always disappointed in people that run around attempting to
    > > dissuade folks from learning or trying anything new.
    > >
    > >
    > >
    > >
    > >
    > > "jbirnsch " wrote:
    > > >
    > > > I was able to revive my frozen battery just by placing it on the
    > > > charger for a few days. It took a day before it started to
    charge but
    > > > once it broke down the sulfates on the plates it really started
    to take
    > > > a decent charge.
    > > >
    > > > No pulser was needed. Just a cheap shumacher charger. Save your
    stamps
    > > > for furnace filter reminders : )
    > > >
    > > > Jason
    > > >
    > > > To UNSUBSCRIBE, just send mail to:
    > > > basicstamps-unsubscribe@yahoogroups.com
    > > > from the same email address that you subscribed. Text in the
    Subject and Body of the message will be ignored.
    > > >
    > > >
    > > > Your use of Yahoo! Groups is subject to
    http://docs.yahoo.com/info/
    > terms/
  • ArchiverArchiver Posts: 46,084
    edited 2002-12-14 21:28
    As a lead acid battery discharges, lead sulfate crystals form on the
    plate surfaces removing plate area from service. The bonding strength
    of the crystals to the plate is proportional to the degree of discharge
    and the length of time they are allowed to remain.

    Should you hit the battery with an extremely high charging voltage,
    causing sulfate crystals to be blown off of the plates the electrolyte
    is permanently weakened. Starter batteries, owing to their porous
    surfaces will shed plate material in the process.

    Should the high rate charging last long enough, the battery can sustain
    heat damage. The temperature of the positive post of a battery is the
    best place to monitor internal battery temperature provided that it is
    insulated.

    As battery capacity is also a function of battery temperature, a hot
    battery will give you a temporary increase in power. This temporary
    increase in capacity over the battery's real capacity will be lost when
    the battery cools down to ambient temperatures.


    Gel cells:
    Not too many of those around. Most have been superseded by the starved
    electrolyte class (97% saturation of the separators with electrolyte) or
    as they are commonly known as VRLA. Both types will not tolerate any
    charging that would cause the battery to gas.

    True gel cells, if gassed, loses capacity as the gas creates a void on
    the plate surface permanently removing that plate surface from service.

    The Valve Regulated Lead Acid (VRLA) will simply vent critically needed
    water and/or electrolyte resulting in permanent and substantial capacity
    loses.

    VRLA has so far been a challenge to be able to restore. While
    desulfators will increase their capacity, dehydration, loss of acid and
    grid corrosion are major factors in their short life span. As their
    internal connecting members are not submerged in electrolyte, corrosion
    is a major factor in their low service life.



    "Dave Mucha " wrote:
    >
    > Interesting post.
    >
    > I would assume that the battery had not died from sulphantion from
    > normal use.
    >
    > I would also assume that the battery was in good condition before it
    > became frozen. it may not have had a good charge, but it must not
    > have been insulated with highly sulphenated deposits.
    >
    > Obviously, the battey did not suffer catastrophic mechanical failure
    > from the freezing. it MAY have suffered stress fractures.
    >
    > What I can figure out from the posts is that
    >
    > A) deposits DO revert or should I say, the sulphur changes phase from
    > a crystaline solid to a dissolved form. The presence of white
    > deposits and lack of them after chargeing indicate that.
    >
    > B) People who live in rural areas are more resourcefull becasue they
    > need to be. and are often smart enough to think the problem all the
    > way thru. Those who not think it all the way thru offer use neat
    > catch phrases like don't run with sizzors. or check the polarity of
    > the cap before you apply power. Puts new meaning into "you are only
    > as safe as your most unsafe act"
    >
    > C) Jason has multiple setting on his charger. I have a trickle
    > charger for my motorcycle and a 30 amp fully automatic for my car.
    >
    > D) we don't have any "Ted Kennedy" awards for people who happen to
    > kill others by their dumb mistakes. I don't think battery charging
    > constitues a nomination for a Darwin award, unless you were doing in
    > the charging in the basement next to your open paint thinner, while
    > doing a whole body indoor tanning with a kerosene based tanning gel,
    > and ignoring the hissing from your home made hydrogen fuelcell
    > hydrogen generator and then tapping the wires from the charger to
    > test polarity. On your wife's birthday.
    >
    > Now my question.
    >
    > I was told that when you take your dead battery to the service
    > station and they put on the 50amp or 250 amp charger, it will weaken
    > or destroy it.
    >
    > Accepting that non-bonded, non-crystalized sulphur deposits will be
    > be flaked off, not re-disolved, what else would this do ?
    >
    > Do we expose ourselves to the same problem with our gel cells ?
    >
    > Dave
    >
    > --- In basicstamps@yahoogroups.com, "jbirnsch <jbirnsch@v...>"
    > <jbirnsch@v...> wrote:
    > > Don,
    > >
    > > I thawed the battery before I placed it on the charger. I also
    > topped
    > > it off with water to the fill line for each cell. The plates were
    > > deposited with a white looking growth. I set the charger to 2A
    > charge
    > > ant left it there for a day. At first it took very little charge,
    > > around 40mA but after a couple hours it was up to 400mA. The next
    > day I
    > > set it to 10 A charge. I left it there for 2 days. By the end of
    > the
    > > second day the battery was bubbling and slightly warm. Now when I
    > > looked at the plates they were clean and free from deposits.
    > Installed
    > > it into the snowmobile and it started right up.
    > >
    > > Where do you see the danger in this????
    > >
    > > Yes, lead acid battery's will explode but only if a spark is
    > generated
    > > while charging at high amp rating like 50 A. It will ignite the
    > > hydrogen gas from the charging process.
    > >
    > > Any time a person jump starts a car there at risk of an explosion.
    > >
    > > All as I am saying that sometimes you get lucky and save a few
    > bucks.
    > >
    > > Darwin award!!!!! Whatever.......
    > >
    > > I grew up on a dairy farm. If anyone had more a chance to get
    > maimed or
    > > killed it would be me. I still have all of my fingers and toes.
    > >
    > > Jason
    > >
    > > --- In basicstamps@yahoogroups.com, Don Denhardt <dondenhardt@y...>
    > > wrote:
    > > > Please folks - Do not follow Jason's example by placing a frozen
    > battery
    > > > on a charger.
    > > >
    > > > They can explode and you can be severely injured or killed. This
    > > > warning is normally found in every battery charger manual.
    > > >
    > > > When in the Navy and attending electronics school, the
    > instructors had
    > > > stated that for each warning that was placed in the manual
    > someone had
    > > > died. That if we should die, from some new blunder on our part,
    > an
    > > > appropriate warning would be added in the future.
    > > >
    > > > Made sense to me, I read and adhere to warnings.
    > > >
    > > > Jason I'd recommend you for a Darwinian award but I see that you
    > are
    > > > still alive.
    > > >
    > > > Desulfators are not a cure for frozen batteries. Desulfators
    > remove the
    > > > large sulfate crystal growths that cannot be removed by
    > charging. These
    > > > are the crystal formations that eventually grow to the point of
    > lead
    > > > acid battery failure and accounts for over 80% of the failure
    > modes.
    > > >
    > > > If you would like to see the crystals with your naked eye, go out
    > at
    > > > night and shine a flashlight down into a flooded cell. If your
    > battery
    > > > is along the path to this type of failure you will see something
    > pretty
    > > > like diamond dust that sparkles.
    > > >
    > > > I am always disappointed in people that run around attempting to
    > > > dissuade folks from learning or trying anything new.
    > > >
    > > >
    > > >
    > > >
    > > >
    > > > "jbirnsch " wrote:
    > > > >
    > > > > I was able to revive my frozen battery just by placing it on the
    > > > > charger for a few days. It took a day before it started to
    > charge but
    > > > > once it broke down the sulfates on the plates it really started
    > to take
    > > > > a decent charge.
    > > > >
    > > > > No pulser was needed. Just a cheap shumacher charger. Save your
    > stamps
    > > > > for furnace filter reminders : )
    > > > >
    > > > > Jason
    > > > >
    > > > > To UNSUBSCRIBE, just send mail to:
    > > > > basicstamps-unsubscribe@yahoogroups.com
    > > > > from the same email address that you subscribed. Text in the
    > Subject and Body of the message will be ignored.
    > > > >
    > > > >
    > > > > Your use of Yahoo! Groups is subject to
    > http://docs.yahoo.com/info/
    > > terms/
    >
    > To UNSUBSCRIBE, just send mail to:
    > basicstamps-unsubscribe@yahoogroups.com
    > from the same email address that you subscribed. Text in the Subject and Body
    of the message will be ignored.
    >
    >
    > Your use of Yahoo! Groups is subject to http://docs.yahoo.com/info/terms/
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